Search results for "Ac impedance spectra"
showing 2 items of 2 documents
Electric field enhanced water dissociation at the bipolar membrane junction from ac impedance spectra measurements
1998
Abstract Preliminary experimental results of the ac impedance spectra of a bipolar ion-exchange membrane are reported and interpreted on the basis of a previous theoretical model based on the Nernst–Planck/Poisson equations. It is shown that the experiments can provide valuable electrochemical information about the bipolar junction structure and the electric-field enhanced water dissociation phenomenon that occurs at this junction, although the high number of unknown parameters involved makes it difficult to obtain accurate values for the parameters characteristic of this phenomenon.
A Simple Model for Ac Impedance Spectra in Bipolar Membranes
1996
A new model accounting for the ac impedance spectra of synthetic ion-exchange bipolar membranes is presented. The theoretical approach is based on the Nernst−Planck and Poisson equations and applies some of the concepts used in the semiconductor pn junctions to the case of a bipolar membrane. The results presented are the current−voltage curves and the impedance spectra at electric currents above the limiting current. It is shown that the model is able to identify the main contributions to the bipolar membrane impedance and gives valuable information about the bipolar junction structure and its influence on the characteristic parameters involved in the field-enhanced water dissociation phen…